First-order phase transition in Onsager's model of hard rods in R3\mathbb R^3

Primarily AI-generated textHuman understanding: no partsmath-ph — Mathematical Physicsmath.PR — Probability

Contributed by Qidong He ↗

Version 1 / Oct 31, 2026 / CC BY 4.0

Abstract

We prove a first-order transition for hard rods in R3\mathbb R^3 whose orientations vary continuously over the sphere. For every sufficiently small positive ratio of diameter to length, the grand-canonical pressure has a nondifferentiable point, with a jump in number density at the intermediate Onsager scale. Following the phase-pressure strategy of Lebowitz, Mazel, and Presutti, we connect coexistence in the homogeneous Onsager functional to the microscopic pressure through an exact auxiliary-field representation, exponential decay of correlations in the rod gas at fixed auxiliary field, and estimates of the free-energy cost of interfaces between connected families of minimizing angular profiles.

Provenance statement

Astra was prompted to prove the existence of a first-order phase transition for the hard-rod model in the three-dimensional continuum, either via the analytic route by proving the non-differentiability of its thermodynamic potential, or via the probabilistic route by proving the coexistence of a continuum of Gibbs measures. It chose the analytic route and produced a candidate proof in an essentially zero-shot run lasting about six hours, with occasional interruptions due to connection errors. The argument closely resembled the work of Lebowitz, Mazel, and Presutti (1999) on the existence of a liquid-vapor transition in a continuum model. Astra was then directed to make these connections explicit and, more broadly, give appropriate credit to the existing literature. It seems that, in working directly with the grand-canonical pressure, Astra has cleverly circumvented the need to prove continuous symmetry breaking. ***THE RESULT IS NOT HUMAN-VERIFIED***

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References

  1. J. L. Lebowitz, A. E. Mazel, and E. Presutti, Rigorous proof of a liquid-vapor phase transition in a continuum particle system , Physical Review Letters 80 (1998), 4701--4704. https://doi.org/10.1103/PhysRevLett.80.4701.DOI
  2. J. L. Lebowitz, A. Mazel, and E. Presutti, Liquid--vapor phase transitions for systems with finite-range interactions , Journal of Statistical Physics 94 (1999), 955--1025. https://doi.org/10.1023/A:1004591218510.DOI
  3. S. A. Pirogov and Ya. G. Sinai, Phase diagrams of classical lattice systems , Theoretical and Mathematical Physics 25 (1975), 1185--1192. https://doi.org/10.1007/BF01040127.DOI
  4. S. A. Pirogov and Ya. G. Sinai, Phase diagrams of classical lattice systems (continuation) , Theoretical and Mathematical Physics 26 (1976), 39--49. https://doi.org/10.1007/BF01038255.DOI
  5. M. Zahradník, An alternate version of Pirogov--Sinai theory , Communications in Mathematical Physics 93 (1984), 559--581. https://doi.org/10.1007/BF01212295.DOI
  6. L. Onsager, The effects of shape on the interaction of colloidal particles , Annals of the New York Academy of Sciences 51 (1949), 627--659. https://doi.org/10.1111/j.1749-6632.1949.tb27296.x.DOI
  7. M. A. C. Vollmer, Critical points and bifurcations of the three-dimensional Onsager model for liquid crystals , Archive for Rational Mechanics and Analysis 226 (2017), 851--922. https://doi.org/10.1007/s00205-017-1146-8.DOI
  8. R. F. Kayser, Jr. and H. J. Raveché, Bifurcation in Onsager's model of the isotropic-nematic transition , Physical Review A 17 (1978), 2067--2072. https://doi.org/10.1103/PhysRevA.17.2067.DOI
  9. E. Bierstone and P. D. Milman, Semianalytic and subanalytic sets , Publications Mathématiques de l'IHÉS 67 (1988), 5--42. https://www.numdam.org/item/PMIHES_1988__67__5_0.pdf.link
  10. R. L. Stratonovich, A method for the computation of quantum distribution functions , Doklady Akademii Nauk SSSR 115 (1957), 1097--1100. https://www.mathnet.ru/eng/dan22296.link
Show all 40 referencesShow fewer references
  1. J. Hubbard, Calculation of partition functions , Physical Review Letters 3 (1959), 77--78. https://doi.org/10.1103/PhysRevLett.3.77.DOI
  2. J. A. Tropp, The expected norm of a sum of independent random matrices: an elementary approach , in High Dimensional Probability VII , Progress in Probability 71 , Birkhäuser, 2016, 173--202. https://doi.org/10.1007/978-3-319-40519-3_8.DOI
  3. M. Jenssen, W. Perkins, A. Potukuchi, and M. Simkin, The replica symmetric solution for hypergraph independent sets in the critical regime , arXiv:2610.10433v1 (2026). https://arxiv.org/abs/2610.10433.arXiv
  4. J. A. Tropp, User-friendly tail bounds for sums of random matrices , Foundations of Computational Mathematics 12 (2012), 389--434. https://tropp.caltech.edu/papers/Tro11-User-Friendly-preprint.pdf.link
  5. C. McDiarmid, On the method of bounded differences , in Surveys in Combinatorics, 1989 , London Mathematical Society Lecture Note Series 141 , Cambridge University Press, 1989, 148--188. https://doi.org/10.1017/CBO9781107359949.008.DOI
  6. R. T. Rockafellar, Convex Analysis , Princeton Mathematical Series, vol. 28, Princeton University Press, Princeton, 1970. https://doi.org/10.1515/9781400873173.DOI
  7. Y. Kondratiev, T. Kuna, and N. Ohlerich, Spectral gap for Glauber type dynamics for a special class of potentials , Electronic Journal of Probability 18 (2013), no. 42, 1--18. https://doi.org/10.1214/EJP.v18-2260.DOI
  8. Nguyen Xuan Xanh and H. Zessin, Integral and differential characterizations of the Gibbs process , Mathematische Nachrichten 88 (1979), 105--115. https://doi.org/10.1002/mana.19790880109.DOI
  9. J. M. Combes and L. Thomas, Asymptotic behaviour of eigenfunctions for multiparticle Schrödinger operators , Communications in Mathematical Physics 34 (1973), 251--270. https://doi.org/10.1007/BF01646473.DOI
  10. B. Helffer and J. Sjöstrand, On the correlation for Kac-like models in the convex case , Journal of Statistical Physics 74 (1994), 349--409. https://doi.org/10.1007/BF02186817.DOI
  11. G. Thompson, Killing tensors in spaces of constant curvature , Journal of Mathematical Physics 27 (1986), 2693--2699. https://doi.org/10.1063/1.527288.DOI
  12. K. Kuratowski and C. Ryll-Nardzewski, A general theorem on selectors , Bulletin de l'Académie Polonaise des Sciences, Série des Sciences Mathématiques, Astronomiques et Physiques 13 (1965), 397--403.
  13. J. M. Danskin, The theory of max-min, with applications , SIAM Journal on Applied Mathematics 14 (1966), 641--664. https://doi.org/10.1137/0114053.DOI
  14. O. Penrose, Convergence of fugacity expansions for classical systems , in Statistical Mechanics: Foundations and Applications , T. A. Bak (ed.), Benjamin, New York, 1967, pp. 101--109.
  15. R. Kotecký and D. Preiss, Cluster expansion for abstract polymer models , Communications in Mathematical Physics 103 (1986), 491--498. https://doi.org/10.1007/BF01211762.DOI
  16. R. Fernández and A. Procacci, Cluster expansion for abstract polymer models: new bounds from an old approach , Communications in Mathematical Physics 274 (2007), 123--140. https://webspace.science.uu.nl/~ferna107/papers/ferpro07.pdf.link
  17. R. L. Dobrushin, Prescribing a system of random variables by conditional distributions , Theory of Probability and its Applications 15 (1970), 458--486. https://doi.org/10.1137/1115049.DOI
  18. O. K. Kozlov, Gibbs description of a system of random variables , Problems of Information Transmission 10 (1974), 258--265. Russian original: Problemy Peredachi Informatsii 10 (3) (1974), 94--103. https://www.mathnet.ru/eng/ppi1046.link
  19. W. G. Sullivan, Potentials for almost Markovian random fields , Communications in Mathematical Physics 33 (1973), 61--74. https://doi.org/10.1007/BF01645607.DOI
  20. D. Ruelle, Classical statistical mechanics of a system of particles , Helvetica Physica Acta 36 (1963), 183--197. https://www.e-periodica.ch/digbib/view?pid=hpa-001:1963:36::1128.link
  21. D. W. Robinson and D. Ruelle, Mean entropy of states in classical statistical mechanics , Communications in Mathematical Physics 5 (1967), 288--300. https://www.ihes.fr/~ruelle/PUBLICATIONS/[17].pdf.link
  22. G. Călinescu, H. Karloff, and Y. Rabani, Approximation algorithms for the 0-extension problem , SIAM Journal on Computing 34 (2004/05), 358--372. https://doi.org/10.1137/S0097539701395978.DOI
  23. M. Mendel and A. Naor, Ramsey partitions and proximity data structures , Journal of the European Mathematical Society 9 (2007), 253--275. https://doi.org/10.4171/JEMS/79.DOI
  24. O. E. Lanford III and D. Ruelle, Observables at infinity and states with short range correlations in statistical mechanics , Communications in Mathematical Physics 13 (1969), 194--215. https://www.ihes.fr/~ruelle/PUBLICATIONS/[26].pdf.link
  25. D. Ruelle, A variational formulation of equilibrium statistical mechanics and the Gibbs phase rule , Communications in Mathematical Physics 5 (1967), 324--329. https://www.ihes.fr/~ruelle/PUBLICATIONS/[18].pdf.link
  26. A. Hatcher, Algebraic Topology , Cambridge University Press, 2002. https://pi.math.cornell.edu/~hatcher/AT/AT.pdf.link
  27. M. Disertori and A. Giuliani, The nematic phase of a system of long hard rods , Communications in Mathematical Physics 323 (2013), 143--175. https://doi.org/10.1007/s00220-013-1767-1.DOI
  28. M. Disertori, A. Giuliani, and I. Jauslin, Plate-nematic phase in three dimensions , Communications in Mathematical Physics 373 (2020), 327--356. https://doi.org/10.1007/s00220-019-03543-z.DOI
  29. R. Peierls, On Ising's model of ferromagnetism , Proceedings of the Cambridge Philosophical Society 32 (1936), 477--481. https://doi.org/10.1017/S0305004100019174.DOI
  30. L. H. Loomis and H. Whitney, An inequality related to the isoperimetric inequality , Bulletin of the American Mathematical Society 55 (1949), 961--962. https://doi.org/10.1090/S0002-9904-1949-09320-5.DOI

Version history

  1. v1Submitted by Qidong HeInitial depositCurrentOct 30, 2026